The SGTE Casebook Thermodynamics at Work 2nd Edition by Klaus Hack ISBN 1845693957 9781845693954

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Product details:

ISBN 10: 1845693957
ISBN 13: 9781845693954
Author: Klaus Hack

The Scientific Group Thermodata Europe (SGTE) is a consortium of European and North American research groups developing thermodynamic databases and software to model the thermodynamic properties of metals and other materials. Understanding these properties is critical to improving the processing of metals and their performance in such areas as resistance to high-temperature corrosion.

This substantially revised new edition explores both the theoretical background to thermodynamic modelling and its wide range of practical applications. These applications include the analysis of hot salt and other types of high-temperature corrosion, understanding the loss of corrosion resistance in stainless and other types of steel, the processing of steels, as well as the use of thermodynamics to improve the functionality of materials for microelectronics and lighting applications, and in the analysis of nuclear safety issues. New case studies also illustrate applications to kinetically-controlled processes such as the solidification and heat treatment of alloys as well as the production of silicon and titanium oxide pigment.

The SGTE casebook is a valuable reference for those manufacturing steels and other materials, those using materials in high-temperature applications such as the power industry and in other areas such as microelectronics and lighting.

The SGTE Casebook Thermodynamics at Work 2nd Table of contents:

Part I: Theoretical Background

I.1 Basic Thermochemical Relationships

• I.1.1 Introduction

• I.1.2 Thermochemistry of Stoichiometric Reactions

• I.1.3 Thermochemistry of Complex Systems

• I.1.4 Activities of Stable and Metastable Phases

• I.1.5 Extensive Property Balances

• I.1.6 References

I.2 Models and Data

• I.2.1 Introduction

• I.2.2 Gibbs Energy Data for Pure Stoichiometric Substances

• I.2.3 Conclusion

• I.2.4 Relative Data

• I.2.5 Solution Phases

• I.2.6 References

I.3 Phase Diagrams

• I.3.1 Introduction: Types of Phase Diagrams

• I.3.2 Zero-Phase-Fraction Lines

• I.3.3 Beyond Classical Phase Diagrams

• I.3.4 The Phase Rule

• I.3.5 Conclusions

• I.3.6 References

I.4 Summarising Mathematical Relationships Between the Gibbs Energy and Other Thermodynamic Information

• I.4.1 Reference

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Part II: Applications in Material Science and Processes

II.1 Hot Salt Corrosion of Superalloys

• II.1.1 Introduction

• II.1.2 Data Used for the Calculations

• II.1.3 The Gas–Salt Equilibrium

• II.1.4 Interaction of Gas and Salt with Cr2O3

• II.1.5 Limitations of Data and Calculated Results

• II.1.6 Extension to Higher-Order Systems

• II.1.7 Future Developments

• II.1.8 Acknowledgements

• II.1.9 References

II.2 Computer-Assisted Development of High-Speed Steels

• II.2.1 Introduction

• II.2.2 Background

• II.2.3 Calculation

• II.2.4 Discussion

• II.2.5 Reference

II.3 Using Calculated Phase Diagrams in the Selection of the Composition of Cemented WC Tools

• II.3.1 Introduction: Background to the Problem

• II.3.2 Region of Favourable Carbon Contents

• II.3.3 Effects of Replacing Co by Fe and Ni

• II.3.4 Favourable Carbon Contents of a Family of Alloys

• II.3.5 Conclusions

• II.3.6 References

II.4 Prediction of Loss of Corrosion Resistance in Austenitic Stainless Steels

• II.4.1 Introduction

• II.4.2 Theory

• II.4.3 Results

• II.4.4 Discussion

• II.4.5 Method of Plotting Diagrams

• II.4.6 Database

• II.4.7 References

II.5 Prediction of a Quasiternary Section of a Quaternary Phase Diagram

• II.5.1 Introduction

• II.5.2 Solid Phases

• II.5.3 Modelling

• II.5.4 Results

• II.5.5 References

II.6 Hot Isostatic Pressing of Al–Ni Alloys

• II.6.1 Introduction

• II.6.2 Generalised Clausius–Clapeyron Equation

• II.6.3 Application to the Ni–Al Equilibrium

• II.6.4 Conclusions

• II.6.5 Acknowledgement

• II.6.6 References

II.7 Thermodynamics in Microelectronics

• II.7.1 Introduction

• II.7.2 Thin-Film Deposition of SrTiO3 and Interface Stability with Si

• II.7.3 Reactive Ion Etching of HfO2 Dielectric Films

• II.7.4 Annealing of Amorphous Ru–Si–O and Ir–Si–O Thin Films

• II.7.5 Conclusions

• II.7.6 References

(…and so on through all II sections II.8 to II.27, formatted similarly.)

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Part III: Process Modelling – Theoretical Background

III.1 Introduction

III.2 The Gulliver–Scheil Method for the Calculation of Solidification Paths

• III.2.1 Reference

III.3 Diffusion in Multicomponent Phases

• III.3.1 Introduction

• III.3.2 Phenomenological Treatment

• III.3.3 Analysis of Experimental Data: The General Database

• III.3.4 References

III.4 Simulation of Dynamic and Steady-State Processes

• III.4.1 Introduction

• III.4.2 Concept of Modelling Processes Using Simple Unit Operations

• III.4.3 General Description of the Reactor Model

• III.4.4 The Control of Material Flows

• III.4.5 Conclusions

• III.4.6 References

III.5 Setting Kinetic Controls for Complex Equilibrium Calculations

• III.5.1 Introduction

• III.5.2 The Basic Concept

• III.5.3 Simple Equilibrium Calculations

• III.5.4 References

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Part IV: Process Modelling – Application Cases

IV.1 Calculation of Solidification Paths for Multicomponent Systems

• IV.1.1 Introduction: Description of the Phase Diagram

• IV.1.2 Solidification Paths

• IV.1.3 References

IV.2 Computational Phase Studies in Commercial Aluminium and Magnesium Alloys

• IV.2.1 Introduction

• IV.2.2 Thermodynamic Calculations for Ternary Subsystems

• IV.2.3 Conclusions

• IV.2.4 Acknowledgement

• IV.2.5 References

IV.3 Multicomponent Diffusion in Compound Steel

• IV.3.1 Introduction

• IV.3.2 Numerical Calculation of Diffusion Between Stainless Steel and Tempering Steel

• IV.3.3 Calculation of Partial Equilibrium Between Carbon Steel and Alloy Steel

• IV.3.4 Summary

• IV.3.5 References

IV.4 Melting of a Tool Steel

• IV.4.1 Introduction

• IV.4.2 Calculation

• IV.4.3 Discussion

• IV.4.4 Conclusions

• IV.4.5 Acknowledgement

• IV.4.6 References

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Tags: Klaus Hack, SGTE, Thermodynamics