Organometallic Chemistry Research Perspectives 1st Edition by Richard P Irwin ISBN 160021780X 978-1600217807

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Product details:

ISBN 10: 160021780X 

ISBN 13: 978-1600217807

Author: Richard P. Irwin

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers. This book presents leading-edge new research in the field.

Table of contents:

1. Polyhedral Boron Hydrides in Use – Current Status and Perspectives

2. Hydrosilylation of CH₂=CH Groups Immobilized on the Interlayer Surface of an Ion-Exchangeable Layered Perovskite with Hydrochlorosilanes and Related Reagents

3. Use of Electrochemistry and Palladium Catalysts for an Efficient Synthesis of Carbonyl Compounds

4. Mixed Transition Metal Acetylides with Different Metals Connected by Carbon-Rich Bridging Units – On the Way to Heteromultimetallic Organometallics

5. Recent Advances in Organometallic Materials Derived from Ferrocenylacetylide

6. The Bio-Organometallic Chemistry of 2Fe–2S Models Related to Iron Hydrogenase Active Site

7. Recent Advances in Organotin(IV) Complexes Containing Sn–S Bonds

8. Organometallic Complexes of Rhodium(I), Iridium(I), and Ruthenium(II) Containing Hemilabile Functionalized Phosphine-Chalcogen Donor Ligands

9. Electronic Properties of Transition Metal Carbene and Silylene Complexes – A Quantum Chemical Study on Selected Model Complexes

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Tags: Richard P Irwin, Organometallic, Chemistry, Research, Perspectives