Organic Redox Systems Synthesis Properties and Applications 1st Edition by Tohru Nishinaga – Ebook PDF Instant Download/Delivery: 1118858743, 9781118858745
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Product details:
ISBN 10: 1118858743
ISBN 13: 9781118858745
Author: Tohru Nishinaga
Organic Redox Systems Synthesis Properties and Applications 1st Table of contents:
1 Introduction: Basic Concepts and a Brief History of Organic Redox Systems
1.1 Redox reaction of organic molecules
1.2 Redox potential in nonaqueous solvents
1.3 A brief history of organic redox compounds
References
2 Redox-Mediated Reversible σ‑Bond Formation/Cleavage
2.1 Dynamic redox (“DyRex”) systems
2.2 Advanced electrochromic response of “endo”-type DyRex systems exhibiting redox switching of a σ‑bond
2.3 Advanced electrochromic response of “exo”-type DyRex systems exhibiting redox switching of a σ‑bond
2.4 Prospect: Redox systems with multiple DyRex units
References
3 Redox-Controlled Intramolecular Motions Triggered by π‑Dimerization and Pimerization Processes
3.1 Introduction
3.2 Oligothiophenes
3.3 Phenothiazine
3.4 Naphthalene and perylene bisimides
3.5 para‑Phenylenediamine
3.6 Pyridinyl radicals
3.7 Viologen derivatives
3.8 Verdazyl
3.9 Phenalenyl
3.10 Porphyrins
3.11 Benzenoid
3.12 Cyclophane
3.13 Tetrathiafulvalene
3.14 Conclusion
Acknowledgments
References
4 Tetrathiafulvalene: A Redox Unit for Functional Materials and a Building Block for Supramolecular Self‑Assembly
4.1 Introduction: past and present of TTF chemistry
4.2 Basic redox properties of TTF and stacked TTF
4.3 TTF as a faithful redox-active unit in functional materials
4.4 Electroconducting properties of TTF derivatives based on supramolecular self-assembly
4.5 Summary and outlook
References
5 Robust Aromatic Cation Radicals as Redox Tunable Oxidants
5.1 Introduction
5.2 Designing molecules for the formation of stable cation radicals (CRs)—a case study
5.3 Methods of preparative isolation of aromatic cation radicals
5.4 Quantitative oxidation of electron donors using as one-electron oxidant
5.5 Readily available electron donors for the redox‑tunable aromatic oxidants
5.6 Conclusion
References
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