Nitrosation Reactions and the Chemistry of Nitric Oxide 1st Edition by DLH Williams ISBN 0444517219 9780444517210

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ISBN 10: 0444517219 
ISBN 13: 9780444517210
Author: DLH Williams

Since 1988, there has been much literature published on the chemistry of nitric oxide, particularly in the field of S-nitrosation and the chemistry of S-nitroso compounds. Written by a chemist for the chemistry community, this book provides an update of the chemistry of nitrosation reactions, dealing with both the synthetic and mechanistic aspects of these reactions. It also looks at the chemistry of nitric oxide in relation to the amazing biological properties of this simple diatomic molecule, which were unknown until around 1990.

Nitrosation Reactions and the Chemistry of Nitric Oxide 1st Table of contents:

Chapter 1. Reagents effecting nitrosation
1.1. Nitrous acid
1.2. Nitrosyl halides HalNO
1.3. Nitrosonium salts NO+X-
1.4. Alkyl nitrites RONO
1.5. N-Nitrososulfonamides RSO2N(NO)R’
1.6. Nitrogen oxides
1.7. Miscellaneous reagents
Chapter 2. Nitrosation at nitrogen centres
2.1. Primary aromatic amines
2.2. Primary aliphatic amines
2.3. Secondary amines
2.4. Tertiary amines
2.5. Amides and related compounds
2.6. Other nitrogen-containing compounds
Chapter 3. The reactions of N-nitrosamines and related compounds
3.1. Rearrangement of aromatic N-nitrosamines Ar(R)NNO (the Fischer-Hepp rearrangement)
3.2. Denitrosation of nitrosamines R(R’)NNO
3.3. Denitrosation of nitrosamides RCON(NO)R’
3.4. Denitrosation of nitrososulfonamides ArSO2N(NO)R
3.5. Carcinogenic properties of N-nitroso compounds
Chapter 4. Aliphatic and alicyclic C-nitrosation
4.1. Nitrosation of ketones
4.2. Nitrosation of other carbonyl compounds
4.3. Nitrosation of nitroalkanes
4.4. Nitrosation of carbanions
4.5. Addition to alkenes
Chapter 5. Aromatic C-nitrosation
5.1. Products of the reactions
5.2. Reaction mechanisms
5.3 Nitrous acid-catalysed nitration reactions
Chapter 6. O-Nitrosation
6.1. Nitrosation of alcohols
6.2. Nitrosation of hydrogen peroxide
6.3. Nitrosation of ascorbic acid
6.4. Other O-nitrosation reactions
Chapter 7. S-Nitrosation
7.1. Nitrosation of thiols
7.2. Nitrosation of thiocarbonyls
7.3. Nitrosation of organic sulfides
7.4. Nitrosation of sulfmic acids
7.5. Nitrosation of thiocyanate ion
7.6. Nitrosation of sulfite/bisulfite
7.7. Nitrosation of thiosulfate ion
7.8. Nitrosation of inorganic sulfide
Chapter 8. Synthesis, properties and reactions of S-nitrosothiols
8.1. Synthesis
8.2. Physical properties
8.3. Thermal and photochemical decomposition
8.4. Decomposition in aqueous solution
8.5. Reaction with nucleophiles
8.6. Detection and quantitative determination of S-nitrosothiols
Chapter 9. Nitrosation involving metal-nitrosyl complexes
9.1. Sodium nitroprusside (pentacyanonitrosylferrate II)
9.2. Other metal nitrosyls
9.3. Iron-sulfur cluster nitrosyls
9.4. Nitrosation of nucleophiles co-ordinated to metals
Chapter 10. The biological chemistry of nitric oxide
10.1. Background
10.2. Reactions of nitric oxide with oxygen and superoxide
10.3. Reactions of nitric oxide with haem proteins
10.4. Reactions of nitric oxide with thiolate ion
10.5. Analytical methods for the determination of nitric oxide
Chapter 11. Nitric oxide in biological systems
11.1. Biological properties of nitric oxide
11.2. Biosynthesis of nitric oxide
11.3. NO synthase enzymes
11.4. Nitric oxide in the treatment of foods
Chapter 12. Nitric oxide-releasing compounds (NO donors)
12.1. Organic nitrates
12.2. Organic nitrites
12.3. S-Nitrosothiols
12.4. Inorganic nitrosyl complexes
12.5. NONOates (Diazeniumdiolates)
12.6. Sydnonimines
12.7. Furoxans (oxadiazoles)
12.8. Hydroxyurea
12.9. Other NO-donors
Chapter 13. Nitroxyl (HNO) and the nitroxyl anion (NO-)
13.1. Generation of HNO/NO-
13.2. Physical and chemical properties of HNO/NO”
13.3. Determination of HNO/NO-
13.4. Biological implications

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Tags: DLH Williams, Nitrosation Reactions, Chemistry, Nitric Oxide