Nanotechnology in Cement Based Construction 1st Edition by Antonella DAlessandro, Annibale Luigi Materazzi, Filippo Ubertini – Ebook PDF Instant Download/Delivery: 9814800767, 9789814800761
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ISBN 10: 9814800767
ISBN 13: 9789814800761
Author: Antonella DAlessandro, Annibale Luigi Materazzi, Filippo Ubertini
Nanotechnology in Cement Based Construction 1st Table of contents:
Part I Advanced Cement-Based Composites
1 Nanoinclusions for Cementitious Materials
1.1 Introduction
1.2 Dispersion of Nanoinclusions in a Cementitious Matrix
1.3 Nanoinclusions for Cement-Based Materials
1.3.1 Carbon-Based Inclusions
1.3.1.1 Carbon nanotubes
1.3.1.2 Carbon nanofibers
1.3.1.3 Graphene nanoplatelets
1.3.1.4 Carbon black
1.3.1.5 Graphene oxide
1.3.2 Metallic Nanoinclusions
1.3.2.1 Nano-TiO2
1.3.2.2 Nano-Fe2O3
1.3.2.3 Silver nanoparticles
1.3.2.4 Nano-Al2O3
1.3.2.5 Nano-ZnO
1.3.2.6 Nano-ZrO2
1.3.2.7 Nano-MgO
1.3.3 Noncarbon Nanoinclusions
1.3.3.1 Nano-SiO2
1.3.3.2 Nano-CaCO2
1.3.3.3 Nanoclay
1.3.3.4 Cement nanoparticles
1.4 Safety of Nanomaterials
1.5 Discussion and Conclusion
2 Dispersion Techniques of Nanoinclusions in Cement Matrixes
2.1 Carbon Nanotubes: Chemical Structure and Properties
2.2 Dispersion Techniques of Carbon Nanotubes: Similia Similibus Solvuntur?
2.2.1 Physical Methods for CNT Dispersion
2.2.1.1 Ultrasonication physical method
2.2.2 Chemical Methods for CNT Dispersion
2.2.2.1 Surfactants: structure, properties, and solubilizing capabilities
2.3 Dispersion of Carbon Nanotubes in Water with Surfactants: Similia Similibus Solvuntur (with the Help of Ultrasonication)
2.3.1 Optimization of CNT Dispersion with Surfactants
2.3.1.1 Commercially available surfactants for CNT dispersions
2.3.1.2 Increasing CNT dispersion with the use of properly designed surfactants
3 Use of Styrene Ethylene Butylene Styrene for Accelerated Percolation in Composite Cement–Based Sensors Filled with Carbon Black
3.1 Introduction
3.2 SEBS-CB Sensors
3.2.1 Materials
3.2.2 Sensor Fabrication
3.3 Methodology
3.3.1 Mix Proportions
3.3.2 Quality Control
3.3.3 Measurements
3.3.4 Electromechanical Model
3.4 Results and Discussion
3.4.1 Percolation Thresholds
3.4.2 Strain Sensitivity
3.5 Conclusion
4 Advancements in Silica Aerogel–Based Mortars
4.1 Introduction
4.1.1 Nanomaterials
4.2 Silica-Based Aerogel
4.3 Aerogel-Based Mortars
4.4 Performance of Aerogel-Based Mortars
4.5 Conclusions
5 Multifunctional Cement-Based Carbon Nanocomposites
5.1 Introduction
5.2 Design and Manufacture of Multifunctional Cement-Based Carbon Nanocomposites
5.3 Behaviors of Multifunctional Cement-Based Carbon Nanocomposites
5.3.1 Mechanical Behaviors
5.3.2 Electrically Conductive Behavior
5.3.3 Sensing Behavior
5.3.4 Damping Behavior
5.3.5 Electromagnetic Shielding/Absorbing Behaviors
5.3.6 Self-Heating Behavior
5.3.7 Durability
5.4 Conclusions
6 Analysis and Modeling of Electromechanical Properties of Cement-Based Nanocomposites
6.1 Introduction
6.2 Electrically Conductive and Electromechanical Mechanisms
6.2.1 Basic Principles of Electrical Conduction
6.2.1.1 Contacting conduction
6.2.1.2 Tunneling conduction and/or field emission conduction
6.2.1.3 Ionic conduction
6.2.2 Electrically Conductive Mechanisms
6.2.3 Electromechanical Mechanisms
6.3 Analysis of Electromechanical Properties
6.3.1 Electrical Resistivity
6.3.2 Impedance or Electrical Reactance
6.3.3 Electric Capacitance
6.3.4 Electrical Impedance Tomography
6.4 Modeling of Electromechanical Properties
6.4.1 Model Based on Tunneling Conduction
6.4.2 Model Based on Field Emission Conduction
6.4.3 Model Based on a Lumped Circuit
6.5 Conclusion
7 Evaluation of Mechanical Properties of Cement-Based Composites with Nanomaterials
7.1 Introduction
7.2 Nanosilica
7.3 Nanotitania
7.4 Nanoalumina
7.5 Nano–Iron Oxide
7.6 Nanoclay
7.7 Nanocarbon Materials
7.7.1 Graphene Nanoplatelets
7.7.2 Carbon Nanofibers
7.7.3 Carbon Nanotubes
7.8 Other Nanoparticles
7.9 Future Perspective
8 Micromechanics Modeling of Nanomodified Cement-Based Composites: Carbon Nanotubes
8.1 Introduction and Synopsis
8.2 Micromechanics Modeling of the Mechanical Properties of Nanomodified Composites
8.2.1 Fundamentals of Mean-Field Homogenization
8.2.2 Eshelby’s Equivalent Inclusion
8.2.3 The Mori–Tanaka Approach
8.2.4 Self-Consistent Effective-Medium Approach
8.2.5 Extended Eshelby–Mori–Tanaka Approaches
8.2.6 Modeling of CNT Waviness
8.2.7 Modeling of CNT Agglomeration
8.3 Micromechanics Modeling of the Electrical Properties of CNT-Reinforced Composites
8.3.1 Physical Mechanisms Governing the Electrical Conductivity of CNT-Reinforced Composites
8.3.1.1 Tunneling resistance: thickness and conductivity of the interface
8.3.1.2 Nanoscale composite cylinder model for CNTs
8.3.2 Percolation Threshold Estimates
8.3.3 Micromechanics Model for the Overall Conductivity of CNT-Reinforced Composites
8.3.3.1 Waviness and agglomeration effects
8.3.4 Micromechanics Model for the Piezoresistivity of CNT-Reinforced Composites
8.3.4.1 Volume expansion and reorientation of CNTs
8.3.4.2 Change in the conductive networks
8.3.4.3 Change in the tunneling resistance
8.4 Summary
9 Use of Carbon Cement–Based Sensors for Dynamic Monitoring of Structures
9.1 Introduction
9.2 State of the Art of Nanomodified Structures
9.3 Cement-Based Sensors for Structural Health Monitoring
9.4 Structures with Embedded Cement-Based Sensors
9.5 Structures Made of Nanomodified Cement-Based Materials
9.6 Comments
9.7 Conclusion
Part II Innovative Applications of Advanced Cement-Based Nanocomposites
10 Cement-Based Piezoresistive Sensors for Structural Monitoring
10.1 Introduction
10.2 Various Types of Cement-Based Sensors
10.2.1 Piezoresistivity
10.2.2 Cement-Based Composites
10.2.3 Carbon-Based Materials (Conductive Fillers)
10.2.4 Dispersion of Carbon-Based Nanomaterials in Cement-Based Composites
10.2.5 Preparation of Cement-Based Sensors and Test Configurations
10.2.6 Self-Sensing Properties by Various Carbon-Based Materials
10.3 Practical Applications of Cement-Based Sensors
10.4 Conclusions
11 Enhancing PCM Cement-Based Composites with Nanoparticles
11.1 Introduction
11.2 Incorporation of PCM in Concrete, Mortar, or Cement
11.3 Enhancing PCM Microcapsules with Nanoparticles for Cement-Based Composites
12 Cement-Based Composites with PCMs and Nanoinclusions for Thermal Storage
12.1 Introduction
12.2 Thermal Energy Storage
12.2.1 Sensible Heat Thermal Storage
12.2.2 Latent Heat Thermal Storage
12.3 Phase Change Materials
12.4 Cement-Based Composites with PCMs
12.4.1 Incorporation of PCMs in Cement-Based Materials Obtained with the Immersion Method
12.4.2 Incorporation of PCMs in Cement-Based Materials Obtained with Direct Mixing
12.4.3 Incorporation of PCMs in Cement-Based Materials Obtained with the Impregnation Method
12.5 PCMs and Nanoinclusions for Cement-Based Materials
12.5.1 Selection of PCMs
12.5.2 Selection of Nanoparticles
12.5.3 PCMs and Nanoinclusions for Cement-Based Materials
12.5.4 NEPCM-Cement-Based Materials for Building and Construction Applications
12.5.5 Recent Developments in NEPCM-Cement-Based Materials for High-Temperature Thermal Storage
12.6 Conclusions
13 Self-Heating Conductive Cement-Based Nanomaterials
13.1 Introduction
13.2 Heating/Cooling Model
13.3 Stage of Heating Produced by the Application of Electric Current
13.4 Stage of Cooling
14 Functional Cementitious Composites for Energy Harvesting and Civil Engineering Applications: An Overview
14.1 Introduction
14.2 Composite Materials and Their Constituents
14.2.1 Major Phases
14.2.1.1 Matrix phase
14.2.1.2 Dispersed (reinforcing) phase
14.2.1.3 Interface in the composite structure
14.2.2 Design of Composites: Connectivity Models
14.3 Composite Materials with Piezoelectric, Ferroelectric, and Pyroelectric Functionalities
14.3.1 Classification
14.3.2 Physics and Chemistry of Composite Materials
14.4 Fabrication of Composites
14.4.1 Fabrication of Polymer-Ceramic Composites
14.4.2 Fabrication of Cement-Ceramic Composites
14.5 Ambient Energy Harvesting and Structural Health Monitoring of Civil Structures via Cement Nanocomposites
14.5.1 Energy Harvesting via Cement Nanocomposites
14.5.1.1 Single-crystal-based materials
14.5.1.2 Polycrystalline-based materials
14.5.1.3 Charge storage via the pyroelectric effect
14.5.1.4 Thermal energy harvesting from pavements via modeling and simulation
14.5.1.5 Waste heat harvesting via thermoelectric cement composites
14.5.1.6 Electric power harvesting via application of piezoelectric transducers in pavements
14.5.2 Functional Cement-Based Nanocomposites for Structural Health Monitoring in Civil Engineering and Sensor Applications
14.6 Summary and Future Outlook
15 Addition of Carbon Nanofibers to Cement Pastes for Electromagnetic Interference Shielding in Construction Applications
15.1 Introduction
15.1.1 Shielding by Reflection
15.1.2 Shielding by Absorption
15.1.3 Shielding by Multiple Reflections
15.1.4 Shielding Effectiveness
15.2 Experimental
15.2.1 Materials and Specimens
15.2.2 Testing Procedures
15.3 Results and Discussion
15.4 Conclusions
16 Perspectives and Challenges of Nanocomposites
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Tags: Antonella DAlessandro, Annibale Luigi Materazzi, Filippo Ubertini, Nanotechnology, Construction


