Methods of Non a Amino Acid Synthesis 2nd Edition by Michael Bryant Smith ISBN 1466577924 9781466577923

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ISBN 10: 1466577924 
ISBN 13: 9781466577923
Author: Michael Bryant Smith

Although less common than a-amino acids, non-a-amino acids-where the amino group is not on the carbon immediately adjacent to the carboxyl group but is attached to another carbon in the chain (for example, the � , d carbon)-are components of biologically important molecules, are significant in the pharmaceutical industry, and are useful starting.

Methods of Non a Amino Acid Synthesis 2nd Table of contents:

Chapter 1: Functional Group Exchanges
1.1 Reactions with Ammonia, Amines, or Amine Surrogates
1.1.1 Reaction with Ammonia
1.1.2 Reaction with Amines
1.1.3 Reaction with Amine Surrogates
1.2 Conversion of Carbonyl Compounds to Amines
1.2.1 From β-Keto-Acids or β-Diketones
1.2.2 From Other Keto-Acids or Aldehyde Acids
1.3 Refunctionalization to Generate Carboxyl Groups
1.3.1 Carboxyl Equivalents
1.3.2 Carboxyl-Bearing Carbanions and Ylids
1.3.3 Oxidative Methods
1.4 Refunctionalization of Amino Acids
1.4.1 From α-Amino Acids
1.4.2 From Other Non-α-Amino Acids
1.4.3 N-Alkylation or N-Arylation
1.5 Specialized Methods
1.5.1 Oxidation and Reduction
1.5.2 Rearrangement Reactions
Chapter 2: Cyclic Precursors
2.1 From Lactams or Imides
2.1.1 From β-Lactams
2.1.2 From Other Lactams
2.1.3 From Imides
2.2 From Ketones
2.2.1 Direct Cleavage of Cyclic Ketones
2.2.2 Via Rearrangement Reactions
2.3 From Lactones and Anhydrides
2.3.1 From Lactones
2.3.2 From Anhydrides
2.4 From Heterocycles
2.4.1 Isoxazolidines, Isoxazoles, Oxazolidines, and Oxazine Derivatives
2.4.2 Pyrazole Derivatives
2.4.3 Pyridine, Hydropyridine, and Pyridone Derivatives
2.4.4 From Uracil Derivatives and Cyclic Carbamates
2.4.5 From Thiophene, Thiazolidine, and Oxathiolone Derivatives
2.5 Diels-Alder Strategies
Chapter 3: Conjugate Addition Reactions
3.1 Ammonia and Amine Nucleophiles
3.2 Carbon Nucleophiles
3.2.1 Nitro Enolates and Nitrile Enolates
3.2.2 Addition to Conjugated Nitro Derivatives
3.2.3 Addition of Enamines
Chapter 4: Enolate Anion and Related Reactions
4.1 Acid, Ester, and Malonate Enolate Anion Reactions
4.2 Nitrile Enolate Anions
4.3 Nitroalkane Enolate Anions
4.4 Mukaiyama Type Condensations
4.5 Condensation Reactions Involving Organozinc Intermediates
4.6 Ylid Reactions
Chapter 5: Diastereoselective and Enantioselective Syntheses
5.1 α-Amino Acid Templates
5.2 Non-α-Amino Acid Templates
5.3 Synthesis from Other Starting Materials
5.4 Transformations Using Carbohydrates as Chiral Templates
5.5 Enzymatic Transformations
Chapter 6: Biologically Important Amino Acids
6.1 Peptides and Proteins
6.1.1 As Residues in Peptides and Proteins
6.1.2 As Substrates for Peptides and Proteins
6.1.3 As Residues in Cyclic Peptides
6.2 β-Alanine and Aminopropanoic Acid Compounds
6.3 GABA and Related Compounds
6.4 GABOB and Carnitine
6.5 DAVA (Ava) and Ahx
6.6 Statine and Related Compounds
6.7 Other Biologically Important Amino Acid Derivatives
6.8 Non-α-Amino Acids in Catalysis
Chapter 7: Aminocyclic and Heterocyclic Amino Acids
7.1 Aminocycloalkylcarboxylic Acids from Cyclic Precursors
7.1.1 Lactam-Based Syntheses
7.1.2 Dicarboxylic Acids and Related Precursors
7.2 From Aromatic Precursors
7.3 From Cyclic Ketones
7.4 Cycloaddition Strategies

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Michael Bryant Smith,Amino Acid,Synthesis