Iron Oxides From Nature to Applications 1st Edition by Damien Faivre, Richard B Frankel – Ebook PDF Instant Download/Delivery: 3527338829, 9783527338825
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ISBN 10: 3527338829
ISBN 13: 9783527338825
Author: Damien Faivre, Richard B Frankel
Following a preliminary overview chapter discussing iron oxide minerals along with their unique structures and properties, the text goes on to deal with the formation and transformation of iron oxides, covering geological, synthetic, and biological formation, as well as various physicochemical aspects. Subsequent chapters are devoted to characterization techniques, with a special focus on X-ray-based methods, magnetic measurements, and electron microscopy alongside such traditional methods as IR/Raman and Mossbauer spectroscopy. The final section mainly concerns exciting new applications of magnetic iron oxides, for example in medicine as microswimmers or as water filtration systems, while more conventional uses as pigments or in biology for magnetoreception illustrate the full potential.
A must-read for anyone working in the field.
Iron Oxides From Nature to Applications 1st Table of contents:
Part I Formation, Transformation
2 Geological Occurrences and Relevance of Iron Oxides
France Lagroix, Subir K. Banerjee, and Mike J. Jackson
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2.1 Introduction
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2.2 Elemental Iron: From the Universe to the Earth
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2.3 Residency of Elemental Iron on Earth
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2.4 Mineral Forms of Iron Oxides
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2.5 Occurrence and Geological Relevance of Iron Oxides
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2.6 Iron Oxides in Continental Dust Deposits
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2.7 Concluding Remarks
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Acknowledgments
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References
3 Reductive Dissolution and Reactivity of Ferric (Hydr)oxides: New Insights and Implications for Environmental Redox Processes
Stefan Peiffer and Moli Wan
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3.1 Introduction
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3.2 The Classical Perspective on Reductive Dissolution
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3.3 Electron Transfer at Ferric (Hydr)oxides Surfaces: The Role of Fe(II)
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3.4 Energetics at the Ferric (Hydr)oxide Interface
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3.5 Rate Control: Surface versus Structural Properties
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3.6 Interaction between Dissolved Sulfide and Ferric Hydroxides
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3.7 Implications
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References
4 Formation and Transformation of Iron-Bearing Minerals by Iron(II)-Oxidizing and Iron(III)-Reducing Bacteria
Jennyfer Miot and Marjorie Etique
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4.1 Introduction
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4.2 Biomineralization of Iron through Microbial Fe(II) Oxidation
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4.3 Iron(III) Minerals: Electron Acceptors for Iron-Reducing Bacteria
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4.4 Specific Properties of Iron Biominerals
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4.5 Microbial Fe Redox Cycling: Past, Present, and Future
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4.6 Conclusion
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References
5 Controlled Biomineralization of Magnetite in Bacteria
Elodie C.T. Descamps, Jean-Baptiste Abbé, David Pignol, and Christopher T. Lefèvre
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5.1 Introduction
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5.2 Magnetotactic Bacteria
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5.3 Organization and Role of Magnetosomes
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5.4 Biomineralization of Magnetosomes
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5.5 Mineral Phase of Magnetosomes
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Acknowledgments
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References
6 Ferritin Iron Mineralization and Storage: From Structure to Function
Noam Aronovitz, Michal Neeman, and Raz Zarivach
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6.1 Introduction
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6.2 Basic Structure of Ferritins
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6.3 Iron Storage and Mineralization
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6.4 NMR and MRI Studies of the Ferritin Iron Core
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6.5 Magnetoferritin
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6.6 Ferritin as a Biotechnological Tool
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6.7 Protocol Annexes
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References
7 Iron Oxides in the Human Brain
Joanna F. Collingwood and Neil D. Telling
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7.1 Introduction
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7.2 Iron Oxides Observed in the Human Brain
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7.3 Properties of Iron Oxides in the Brain
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7.4 Stored and Sequestered Iron Oxide in the Human Brain
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7.5 Methods to Detect Iron Oxides in the Brain
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7.6 Tools and Treatments: Manipulating Iron Oxides in the Brain
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7.7 Concluding Remarks
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Acknowledgments
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References
8 The Chiton Radula: A Model System for Versatile Use of Iron Oxides
Derk Joester and Lesley R. Brooker
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8.1 Functional Anatomy of the Mollusk Radula
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8.2 Development of the Radula: Organic Matrix
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8.3 The Discovery of Biominerals in the Radula
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8.4 The Microarchitecture of Chiton Radula Teeth
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8.5 Development of the Chiton Radula: Stages of Biomineralization
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8.6 Development of the Radula: Biological Control
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8.7 Role of Acidic Macromolecules in the Insoluble Organic Matrix
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8.8 Soluble Organic Matrix Composition
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8.9 Selective Deposition of Ferrihydrite in Stage II
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8.10 Conversion of Ferrihydrite to Magnetite in Stage III
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8.11 Phase Transformations in Stage IV
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8.12 Final Functional Architecture
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8.13 Concluding Remarks
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References
9 Mineralization of Goethite in Limpet Radular Teeth
Tina Ukmar-Godec
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9.1 Introduction
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9.2 Structure, Properties, and Function of the Limpet Radula
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9.3 Goethite Produced in the Laboratory
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9.4 Goethite Produced in Limpets
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9.5 Conclusion
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References
10 Synthetic Formation of Iron Oxides
Corinne Chaneac, Anne Duchateau, and Ali Abou-Hassan
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10.1 Introduction
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10.2 Iron Oxide and Oxyhydroxide from Aqueous Ferric Solution
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10.3 Iron Oxide and Oxyhydroxide from Aqueous Ferrous Solution
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10.4 Iron Oxide Synthesis Using Microfluidic Process
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References
11 Oriented Attachment and Nonclassical Formation in Iron Oxides
Jennifer A. Soltis and R. Lee Penn
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11.1 Introduction
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11.2 OA in Iron Oxides in the Literature
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11.3 OA and Phase Transformation
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11.4 Detection and Characterization of Growth by OA
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11.5 Kinetics of Growth by OA
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11.6 Thermodynamics
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11.7 Morphology and Surface Chemistry
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11.8 Forces Governing Assembly
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11.9 Future Work
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References
12 Thermodynamics of Iron Oxides and Oxyhydroxides in Different Environments
Haibo Guo and Amanda S. Barnard
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12.1 Introduction
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12.2 Magnetic Transformations
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12.3 Polymorphic Transformations
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12.4 Summary
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References
Part II Characterization Techniques
13 Introduction to Standard Spectroscopic Methods: XRD, IR/Raman, and Mössbauer
Fernando Vereda
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13.1 Introduction
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13.2 X-Ray Diffraction (XRD)
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13.3 Vibrational Spectroscopy
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13.4 Mössbauer Spectroscopy
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Acknowledgments
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References
14 TEM and Associated Techniques
Tanya Prozorov
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Common Abbreviations
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14.1 Introduction
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14.2 Nanoscale Analysis of Iron Oxides
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14.3 Electron Holography
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14.4 The Near In Situ Approach
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14.5 In Situ Analysis with a Liquid Cell
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Acknowledgment
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References
15 Magnetic Measurements and Characterization
Ann M. Hirt
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15.1 Introduction
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15.2 Summary of Magnetic Properties of Iron Oxides and Iron Hydroxides
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15.3 Induced Magnetization
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15.4 Remanent Magnetization
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15.5 Usage of Magnetic Properties
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15.6 Summary
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References
16 Total X-Ray Scattering and Small-Angle X-ray Scattering for Determining the Structures, Sizes, Shapes, and Aggregation Extents of Iron (Hydr)oxide Nanoparticles
Young-Shin Jun and Byeongdu Lee
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16.1 Introduction
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16.2 Determination of Particle Structures: Total X-Ray Scattering with PDF Analysis
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16.3 Determination of Particle Sizes, Shapes, and Aggregation Extents: SAXS and GISAXS
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16.4 Outlook
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Acknowledgments
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References
17 X-Ray Absorption Fine Structure Spectroscopy in Fe Oxides and Oxyhydroxides
M. Luisa Fdez-Gubieda, Ana García-Prieto, Javier Alonso, and Carlo Meneghini
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17.1 Brief Introduction to XAFS
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17.2 XANES spectroscopy
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17.3 EXAFS Spectroscopy
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17.4 Conclusion and Perspectives
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References
Part III Applications
18 Medical Applications of Iron Oxide Nanoparticles
Amanda K. Andriola Silva, Ana Espinosa, Jelena Kolosnjaj-Tabi, Claire Wilhelm, and Florence Gazeau
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18.1 Introduction
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18.2 IONPs for Imaging
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18.3 Magnetic Drug Targeting
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18.4 IONPs and Tissue Engineering
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18.5 Activation of IONPs with Time-Dependent Magnetic Fields
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18.6 Life Cycle of IONPs
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18.7 Conclusion
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References
19 Iron Nanoparticles for Water Treatment: Is the Future Free or Fixed?
Sarah J. Tesh and Thomas B. Scott
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19.1 Introduction
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19.2 Why Iron?
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19.3 INPs: A Versatile Material for Water Treatment
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19.4 Operational Drivers for Water Treatment
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19.5 Static Nanocomposites
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19.6 What Is Holding Back Static Nanocomposites?
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19.7 Conclusion
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References
20 Actuation of Iron Oxide-Based Nanostructures by External Magnetic Fields
Peter Vach
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20.1 Introduction
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20.2 Nanomachines
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20.3 Guided Self-Assembly
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20.4 Conclusion
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References
21 Iron Oxide-Based Pigments and Their Use in History
Marco Nicola, Chiara Mastrippolito, and Admir Masic
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21.1 Introduction
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21.2 Chemical Composition and Properties of Iron Oxide-Based Pigments
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21.3 Use of Iron Oxide-Based Pigments in History
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21.4 Case Studies
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References
22 Magnetoreception and Magnetotaxis
Mathieu A. Bennet and Stephan H. K. Eder
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22.1 Magnetoreception
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22.2 Magnetotaxis
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