Inorganic Polymeric and Composite Membranes Structure Function and Other Correlations 1st Edition by S Ted Oyama, Susan M Stagg Williams – Ebook PDF Instant Download/Delivery: 044453728, 97804445372877
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ISBN 10: 044453728
ISBN 13: 97804445372877
Author: S Ted Oyama, Susan M Stagg Williams
Inorganic, Polymeric and Composite Membranes: Structure-Function and Other Correlations covers the latest technical advances in topics such as structure-function relationships for polymeric, inorganic, and composite membranes. Leading scientists provide in depth reviews and disseminate cutting-edge research results on correlations but also discuss new materials, characterization, modelling, computational simulation, process concepts, and spectroscopy
Inorganic Polymeric and Composite Membranes Structure Function and Other Correlations 1st Table of contents:
Chapter 1: Correlations
introduction
scientific laws and correlations
principles
theories
laws
properties
effects
equations
dimensionless numbers
criteria
approximations, factor, curves
correlations
important properties in membrane science
examples of correlations in the membrane separation field
summary
acknowledgments
references
Chapter 2: Review of silica membranes for hydrogen separation prepared by chemical vapor deposition
introduction
silica membranes for hydrogen separation
chemical vapor deposition: principles
synthesis of silica membranes via chemical vapor deposition
silica membranes supported on Vycor glass
silica membranes supported on alumina
conclusions
acknowledgments
references
Chapter 3: Amorphous silica membranes for H₂ separation prepared by chemical vapor deposition on hol
introduction
experimental
results and discussion
pure hollow fiber support properties
mesoporous silica layer
amorphous γ-alumina layer
silica precursor and carrier gas flow rate effects on the membrane separation performance
gas separation mechanism
conclusions
acknowledgments
references
Chapter 4: Ab initio studies of silica-based membranes: activation energy of permeation
introduction
previous theoretical studies on dense silica-based membranes
method of calculation
results and discussion
conclusions
acknowledgments
references
Chapter 5: Review of CO₂/CH₄ separation membranes
introduction
discussion
zeolite membranes and carbon molecular sieves
silica membranes
polymeric membranes
mixed-matrix membranes
supported ionic liquid and polyionic membranes
overall results
conclusions
acknowledgments
references
Chapter 6: Gas permeation properties of helium, hydrogen, and polar molecules through microporous silica membranes
introduction
experimental
fabrication of silica and co-doped silica membranes by sol-gel method
gas permeation/separation measurements for silica membranes
results and discussion
improved hydrothermal stability of amorphous silica membranes
helium and hydrogen permeation properties through amorphous silica membranes
permeation properties of polar molecules (NH₃, H₂O) through amorphous silica membranes
conclusions
references
Chapter 7: Correlation between pyrolysis atmosphere and carbon molecular sieve membrane performance
introduction
theory and background
transport in CMS membranes
structure of CMS membranes
effect of pyrolysis atmosphere on separation performance of CMS membranes
experimental
materials
characterization methods
results and discussion
correlation between oxygen exposure and CMS separation performance
correlation between oxygen concentration and CMS separation performance
possible mechanism of oxygen “doping” process during pyrolysis
conclusion
acknowledgements
references
Chapter 8: Review on prospects for energy saving in distillation process with microporous membranes
introduction
potential of membrane separation technology for large-scale reduction in energy consumption
why zeolite membranes are promising
synthesis technique of zeolite membranes
seeding technique (secondary growth method)
masking technique
use of SDA for microstructural optimization
de-watering technology using zeolite membranes
de-watering of alcohol
de-watering of organic acids
de-watering for C1 chemistry
concluding remarks
references
Chapter 9: Xylene separation performance of composition-gradient MFI zeolite membranes
introduction
experimental
bilayer membrane synthesis and characterization
pervaporation experiments
results and discussion
membrane characteristics
binary pervaporation through single and bilayer membranes
reversal of bilayer structure
stability at higher PX feed concentrations
conclusions
acknowledgments
references
Chapter 10: Membrane extraction for biofuel production
introduction
removal of acetic acid from biomass hydrolysates
extraction of 5-hydroxymethylfurfural
glycerol extraction
material and methods
removal of acetic acid from biomass hydrolysates
HMF extraction
glycerol extraction
results
conclusions
acknowledgments
references
Chapter 11: A review of mixed ionic and electronic conducting ceramic membranes as oxygen sources for synthesis gas
introduction
general attributes of oxygen-conducting MIEC ceramic materials
oxygen nonstoichiometry
self-adjusting phase equilibria
chemical expansivity
microstructure of oxygen-MIEC ceramics
common oxygen-MIEC membrane materials
fluorites
perovskites
SCF-based materials
dual-phase composite materials
membrane modifications to improve oxygen flux
surface modifications
membrane thickness reduction
MIEC membranes for synthesis gas production
synthesis gas production overview
benefits of MIEC membranes for synthesis gas production
overview of work to date
effect of reaction temperature on membrane performance
effect of reaction environment on membrane oxygen flux
conclusions
acknowledgments
references
Chapter 12: Critical factors affecting oxygen permeation through dual-phase membranes
introduction
design of dual-phase membranes with high stability and permeability
experimental investigation of dual-phase membranes
pure electronic conductor or mixed conductor?
surface exchange
preparation methods for powders
sintering temperature
ratio between the two phases
other factors
conclusions
acknowledgments
references
Chapter 13: High temperature gas separations using high performance polymers
introduction
experimental
instrumentation
permeability gas testing
positron annihilation lifetime spectroscopy
results and discussion
conclusions
acknowledgments
references
Chapter 14: Using first-principles models to advance development of metal membranes for high temperature applications
introduction
DFT-based modeling of crystalline metal membranes
cluster expansion methods
applications of DFT calculations to crystalline membrane materials
amorphous metal membranes
computational approaches for amorphous metals
amorphous structures
binding energy of interstitial H in amorphous alloys
H-H interactions
H solubility in amorphous alloys
hydrogen diffusion in amorphous alloys
corrected diffusivities
the thermodynamic correction factor
hydrogen permeability through amorphous alloys
conclusion
acknowledgments
references
Chapter 15: High performance ultrafiltration membranes: pore geometry and charge effects
introduction
pore geometry effects
fluid flow
solute transport
pore size distribution effects
electrostatic interactions
fluid flow
solute transport
concentration polarization effects
conclusions
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