Basic Chemical Thermodynamics 5th Edition by E Brian Smith – Ebook PDF Instant Download/Delivery: 1860944469, 9781860944468
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Product details:
ISBN 10: 1860944469
ISBN 13: 9781860944468
Author: E Brian Smith
Basic Chemical Thermodynamics 5th Table of contents:
1 Introduction
1.1 The scope and nature of chemical thermodynamics
1.2 Equilibrium in mechanical systems
1.3 Reversibility and equilibrium
1.4 Why we need thermodynamics
1.5 The mole
1.6 The perfect gas
2 Energy
2.1 Work
2.2 Heat and temperature
2.3 Measurement of temperature
2.4 Heat and molecular motion
2.5 Conservation of energy
2.6 State functions: a digression
2.7 Enthalpy
2.8 Heat capacity
Problems
3 Entropy and equilibrium
3.1 Reversibility and equilibrium: a recapitulation
3.2 Condition of equilibrium
3.3 Entropy
3.4 Entropy as a state function
3.5 Entropy of expansion of a gas
3.6 Entropy changes accompanying heat flow
3.7 Entropy and equilibrium
3.8 A cosmological aside
3.9 Entropy as a function of pressure and temperature
3.10 Molecular basis of entropy
3.11 Statistical basis of the Second Law
3.12 Magnitudes of entropy changes
3.13 Heat engines
Problems
4 Equilibrium in chemical systems
4.1 Free energy
4.2 Gibbs free energy
4.3 Pressure-dependence of free energy
4.4 Temperature variation of free energy
4.5 Phase equilibria
4.6 Clapeyron equation
4.7 Clausius-Clapeyron equation
4.8 The vapour pressure of liquids
4.9 Chemical potential
4.10 Chemical potential and free energy
4.11 Equilibrium between gaseous reactants
4.12 Temperature-dependence of equilibrium constants
4.13 Effect of pressure on equilibrium constants
4.14 Basic results of chemical thermodynamics
4.15 Le Chatelier’s Principle
Problems
5 Determination of thermodynamic quantities
5.1 Hess’s Law
5.2 Standard enthalpies of formation
5.3 Average bond energies
5.4 Temperature-dependence of enthalpy changes
5.5 Standard free energies of formation
5.6 Determination of free-energy changes
5.7 Determination of entropies of substances
5.8 Example of the determination of thermodynamic quantities
5.9 Calculation of thermodynamic quantities at temperatures other than 298 K
5.10 Ellingham diagrams
5.11 Free-energy functions
Problems
6 Ideal solutions
6.1 The ideal solution
6.2 Properties of truly ideal solutions
6.3 Mixtures of liquids
6.4 Ideal solutions of solids in liquids
6.5 Ideal dilute solutions
6.6 Colligative properties
6.7 Freezing-point depression
6.8 Elevation of boiling point
6.9 Osmotic pressure
6.10 Properties of the solute in dilute solutions
6.11 Solubility of solids
Problems
7 Non-ideal solutions
7.1 The concept of activity
7.2 Activity of solids in liquids
7.3 Activity in aqueous solutions
7.4 Chemical equilibria in solution
7.5 Electrochemical cells
7.6 Standard electrode potentials
Problems
8 Thermodynamics of gases
8.1 Expansion of a perfect gas
8.2 Irreversible expansion
8.3 Equation of state of gases
8.4 Joule-Thomson experiment
8.5 Imperfect gases: fugacity
8.6 Calculation of fugacities
Problems
9 The Molecular basis of thermodynamics
9.1 Energy levels
9.2 Microstates
9.3 The Boltzmann factor
9.4 Behaviour of heat capacity
9.5 Partition functions
9.6 Entropy and the partition function
9.7 Calculation of the translational partition function
9.8 The rotational partition function
9.9 Vibrational partition function
9.10 Evaluation of the properties of gaseous nitrogen
9.11 Chemical equilibrium
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