Analytical Electrochemistry in Textiles Woodhead Publishing in Textiles 1st Edition by P Westbroek, G Priniotakis, Paul Kiekens ISBN 0849334853 9780849334856
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ISBN 10: 0849334853
ISBN 13: 9780849334856
Author: P Westbroek, G Priniotakis, Paul Kiekens
Analytical electrochemistry in textiles is divided into four parts. In the first part an overview is given of the theory of electrochemistry as well as of practical considerations. The second part contains chapters in which the development of sensors is described for the optimisation and automation of textile finishing processes. In the third part the fundamentals of textile electrodes, used in a wide variety of applications, are summarised, as well as offering a developed study of a quality control method. Finally, the fourth part of the book is related to the functionalisation of fibres through chemical and electrochemical modification and some applications are given for these types of textile related electrodes.
Written so that both non-electrochemists and non-textile specialists can understand it, Analytical electrochemistry in textiles is an important guide for textile, chemist and material science academics. It will also prove of great benefit for textile manufacturers, processors, dyers, colourists and finishers.
- Provides an overview of the synergy between electrochemistry and textiles
- An invaluable reference tool for textile, chemist and material science academics as well as textile manufacturers, processors, dyers, colourists and finishers
Analytical Electrochemistry in Textiles Woodhead Publishing in Textiles 1st Table of contents:
Part I Theoretical considerations
1 Fundamentals of electrochemistry
1.1 Introduction
1.2 What is an electrochemical reaction?
1.3 Conventions for presentation of electrochemical data
1.4 Classification of electrochemical methods
1.5 Two-electrode setup
1.6 Three-electrode setup
1.7 Charge-transfer and transport phenomena
1.8 References
2 Electrochemical methods
2.1 Introduction
2.2 Potentiometry
2.3 Cyclic voltammetry
2.4 Impedance of electrochemical systems
2.5 Chronoamperometry
2.6 Other voltammetric methods
2.7 References
Part II Electrochemistry in textile finishing
3 Probes for pH measurement and simultaneous cellulose removal and bleaching of textiles with enzyme
3.1 Introduction
3.2 Ion-selective electrodes
3.3 Glass-membrane electrodes
3.4 Simultaneous cellulose removal and bleaching with enzymes
3.5 References
4 Electrochemical behaviour of hydrogen peroxide oxidation: kinetics and mechanisms
4.1 Introduction
4.2 Use of hydrogen peroxide in textile-bleaching processes
4.3 Determination methods of hydrogen peroxide
4.4 Voltammetric behaviour
4.5 Detection of high hydrogen peroxide concentrations with amperometric method
4.6 Theoretical I-E relationship for mechanism 1
4.7 Theoretical I-E relationship for mechanism 2
4.8 The pseudo-limiting-current
4.9 Combination of rate equations of both mechanisms
4.10 References
5 Amperometric detection of hydrogen peroxide in bleaching and washing processes
5.1 Introduction
5.2 Influence of temperature
5.3 Behaviour of the sensor electrode at the laboratory scale
5.4 Behaviour of the sensor in an industrial environment
5.5 Expanding the sensor system for processes occurring at pH <10.5
5.6 References
6 Simultaneous detection of indigo and sodium dithionite for control of dyeing processes
6.1 Introduction
6.2 Basic electrochemical reactions of dithionite and sulphite
6.3 Kinetic limitations in oxidation of dithionite and sulphite
6.4 Mechanism of the charge-transfer kinetics of dithionite oxidation
6.5 Detection of sodium dithionite
6.6 Detection of indigo
6.7 Simultaneous detection of sodium dithionite, sulphite and indigo at a wall-jet electrode
6.8 References
7 Advantages of electrocatalytic reactions in textile applications: example – electrocatalytic oxi
7.1 Introduction
7.2 Electrodeposition of Co(II)TSPc at gold electrodes
7.3 Analysis of the data
7.4 Electrocatalysis with modified gold electrodes towards sodium dithionite
7.5 References
Part III Textile electrodes
8 Intelligent/smart materials and textiles: an overview
8.1 Introduction
8.2 Smart materials
8.3 Intelligent/smart textiles
8.4 Electrotextiles
8.5 Intelligent clothing
8.6 References
9 Characterisation of electrochemical cell for textile electrode studies and quality control
9.1 Introduction
9.2 Characterisation of an electrochemical cell
9.3 Method for quality control of textile electrodes
9.4 Conclusion
9.5 References
10 Electroconductive textile electrodes for detection and analysis of sweat and urine
10.1 Introduction
10.2 Description of the cell configuration
10.3 Conditions for using yarn electrodes
10.4 Cell configuration with immobilised electrolyte solution
10.5 Experiments with artificial sweat and under real-time conditions
10.6 References
Part IV Modified fibres and their applications
11 Chemical metallisation and galvanisation as a method for development of electroconductive polyacr
11.1 Introduction
11.2 Optimisation of process parameters in polyacrylonitrile production for metallisation with nicke
11.3 Optimisation of electroconductive PAN-fibre production
11.4 References
12 Textile fibres used as electrode materials in analytical applications
12.1 Introduction
12.2 A platinum-fibre electrode for detection of Cu(II) and Cu(I) in non-aqueous solution
12.3 Determination of SO2 reactions as a function of pH and its detection at modified carbon-fibre e
12.4 Gold-fibre textile electrodes obtained through chemical modification for the detection of Ce(IV
12.5 References
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